Alexander Winston

This work utilizes electron microscopy-based techniques to examine the radial behavior of solid fission products in plutonium (Pu) bearing mixed oxide (MOX) fuel irradiated to a burnup of 13.7% fissions per initial metal atom (FIMA). Metallic precipitates primarily consist of five fission products: ruthenium (Ru), rhodium (Rh), technetium (Tc), molybdenum (Mo), and palladium (Pd). The five metal precipitates (FMPs) examined in this work have low concentrations of Pd and Mo, with no major compositional differences along the fuel radius. A secondary Pd–Te metallic phase forms in cooler regions of the pellet, likely due to the diffusion of gaseous species away from the central void. X-ray chemical maps indicate that the Pd–Te phase can nucleate on the surface of FMPs before precipitating into separate particles. These particles were also found to alloy with iron (Fe) near the surface of the fuel pellet due to interdiffusion with the stainless-steel cladding. The insoluble perovskite oxide phase was found to form near the central void and at intermediate radial positions, but not at the fuel edge. These findings suggest that solid fission product phases form at varying counts and compositions along the fuel pellet radius, and thus should be considered when describing the thermal behavior of the fuel.