Geoffrey Beausoleil

Recently, high-entropy alloys (HEAs) and multi-principal elemental alloys (MPEAs) have attracted attention as potential new structural materials for in-core nuclear reactor applications, thanks to their structural stability and excellent mechanical properties. However, their multi-phase microstructural behavior under irradiation requires further attention, as it is crucial for understanding the irradiation behavior of the alloys. The current work compares the radiation behaviors of the Al0.3CrFeCuNi (0.3Al) and Al0.8CrFeCuNi (0.8Al) alloys, which were prepared via spark plasma sintering and then irradiated in situ in a transmission electron microscope (TEM) using 1-MeV Kr+ ions and up to 10 displacements per atom (dpa) at room temperature (RT) and at 300°C. Pre-irradiation characterization of the alloys was performed using x-ray diffraction (XRD) and transmission electron microscopy, revealing the formation of major proportions of (face-centered cubic [FCC] + body-centered cubic [BCC]) phases. A higher Al content spurred transformation from the FCC phase to the BCC phase and sparked the formation of ordered phases. While the alloy containing 0.3Al (FCC) exhibited irradiation-induced ordering at both RT and at 300°C, the 0.8Al alloy showed irradiation-induced disordering of the ordered phases at 300°C. The pre- and post-irradiation transmission electron microscopy experiments evidenced how variations in local chemistry and microstructural features in these MPEAs affect the local response to irradiation (at the nm/µm level). This study provides an overview of how structurally and chemically different phases in MPEAs react when under irradiation, affording crucial knowledge for understanding the irradiation resistance of the alloys.