- Nanoindentation Creep Testing and Characterization of High Temperature Irradiated HT-9 Cladding

Principal Investigator
Name:
Joshua Rittenhouse
Email:
[email protected]
Phone:
(208) 526-6918
Team Members:
Name: Institution: Expertise: Status:
Yachun Wang Idaho National Laboratory Electron Microscopy, Fuel Cladding Chemical Interaction (FCCI), Irradiated Cladding, Microstructural Analysis, Tensile Properties Other
Tiankai Yao Idaho National Laboratory Amorphization, Ceramics, Characterization, Corrosion, Environmental Degradation, Grain Growth, High Burnup Fuel, High Density Fuels, Nuclear Fuel, Nuclear Waste, Spark Plasma Sintering, Uranium Compounds Other
Luca Capriotti Idaho National Laboratory Fast Reactor, Fast Reactor MOX Fuel, Fuel Cladding Chemical Interaction (FCCI), HT9, Irradiated Fuels, Oxide Fuels, PIE Other
Experiment Details:
Experiment Title:
Nanoindentation Creep Testing and Characterization of High Temperature Irradiated HT-9 Cladding)
Hypothesis:
Due to a lack of experimental data from which to extract relevant, representative parameters, there exists significant inaccuracies in strain field and creep models of HT-9 cladding when considering scenarios with higher burnup as well as thermal conditions near 600°C. Thus, it is the objective of this work to provide such experimental data and parameters through the testing and characterization of an HT-9 sample previously irradiated in the Fast Flux Test Facility to 25 DPA at 635°C.
Work Description:
All work will be performed in the Irradiated Materials Characterization Laboratory (IMCL) in the Materials and Fuels Complex (MFC) at Idaho National Laboratory (INL). Sample MNT88T which was segmented from the MFF5 195011 fuel pin irradiated in the Fast Flux Test Facility (FFTF) has been selected for this work. The MNT88T sample is an HT-9 cladding sample (fuel slug removed) that has undergone irradiation to 25 DPA at 635°C. This sample has a dose rate of 100 mr/hr at 30cm in terms of gamma radiation. Since the MNT88T sample is already in IMCL no sample transfer or shipping between facilities will need to be considered. The sample has also previously been mounted in Met Mount. Thus, this work will begin by polishing the sample in the IMCL shielded sample preparation area (SSPA) to a degree where the surface finish is conducive to nanoindentation followed by decontamination. A Micro Materials NanoTest Vantage ex-situ nano-indenter will be used for all nanoindentation experiments. Traditional nanoindentation experiments with constant strain rate where load vs. displacement is recorded will be performed at 25°C, 250°C, and 500°C. Nanoindentation based creep experiments will be performed at 300°C, 400°C, and 500°C using a constant load where displacement vs. time is measured. In the case of both the traditional nanoindentation and creep experiments, 5x5 grids of indents will be made with 5 indents being made along the radial axis with 5 indents at each radial position. Following nanoindentation, two TEM foils will be prepared using the FEI Quanta Ga FIB/SEM. The two foils will then be characterized using the Thermo Fisher Scientific Titan Themis probe corrected TEM which will include regular TEM imaging, high resolution TEM imaging, bright field and high angle annular dark field STEM imaging, STEM EDS compositional mapping, and 4D-STEM analysis.
Project Summary
HT-9 is a ferritic/martensitic steel alloy that is a candidate material for use in cladding in various advanced nuclear reactor designs including the Versatile Test Reactor. Although, there have been many successful experiments and studies surrounding the mechanical behavior of HT-9 under irradiation conditions with results from such studies being successfully incorporated into the BISON framework to model creep and simulate strain, there still exists significant inaccuracies to those models in scenarios of elevated temperatures (>600°C) and extended irradiation durations. Such inaccuracies are largely due to parameters from fresh HT-9 being used in the model which do not take into account the remarkable microstructural changes that occur under irradiation in the harsh in-core environment. Thus, it is the objective of this work to provide experimental data and measure such mechanical properties as elasticity from an HT-9 sample that has been previously irradiated in the Fast Flux Test Facility to 25 DPA at 635°C from which such experimental data can be incorporated into the BISON framework to more accurately model creep and simulate strain. Such work will be accomplished through the use of nanoindentation based experiments both in terms of constant strain rate loading as well as constant load creep experiments. Those experiments will be performed at multiple temperatures up to 500°C to obtain clear information of mechanical behavior at such elevated temperatures. The microstructure within the indented regions will be further characterized in TEM to further identify further phenomena contributing to mechanical behavior of heavily irradiated HT-9 cladding. It is expected that such work can be performed over the course of ten days. With such experimental measurements and knowledge, not only will detailed insight be gained into mechanical behavior, but the models can be updated to improve accuracy and provide a further, confident means of material qualification for advanced nuclear reactors.
Relevance
The proposed work aims to contribute towards the continued development and refinement of the BISON framework to accurately and reliably model creep and simulate strain within materials that have excellent candidacy for use in advanced reactor designs. This objective will be accomplished by addressing knowledge gaps when it comes to mechanical behavior of HT-9 cladding that has been heavily irradiated at elevated temperatures. Incorporating many significant, successful experiments, the BISON framework has been able to accurately model creep and simulate strain within an impressive range of conditions. However, in scenarios of extreme burn up and elevated temperatures (>600°C) it has been found that such models contain significant inaccuracies largely due to gaps in experimental data leading to the use of parameters that are not completely representative of such systems. Thus, in order to gain detailed insight into the mechanical behavior of heavily irradiated HT-9 cladding, a sample previously irradiated in the Fast Flux Testing Facility to 25 DPA at 635°C has been selected for nanoindentation based experiments including creep experiments followed by detailed TEM characterization. Such will further the understanding of the mechanical behavior of HT-9 which is a strong candidate as a cladding material for use in advanced nuclear reactors as well as provide critical data towards the enhancement of the capabilities of the BISON framework to accurately model such mechanical behavior. Such modeling capabilities will be crucial in qualifying fuel systems for advanced reactors including those in the Versatile Test Reactor.